Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

美国出口管制下中国外贸风险的省域地理差异     

姜辉 《地理科学》2020,40(10):1618-1626

从总贸易、出口、进口、外资和人员5个视角构建对美风险系数，测度和比较各省区市对美外贸风险的地理差异。结果表明：上海、浙江和福建与美国的进出口贸易规模最大，对美国市场的依赖程度最高，面临的综合外贸风险最大；河南尤其需要防范对美国的出口风险；海南、新疆、天津和西藏等需要加强从美国进口的风险管理；重庆除了需要防范对美出口风险外，还因为实际利用美资最多且依赖程度最大，亟需加强外资风险管理。宁夏和山西虽然从美国的引资规模不大，但是对美资的依赖程度最高，亟需提升外资多元化水平。从人员跨境流动风险来看，上海、北京和浙江面临的风险最大。中国各省区市在应对美国出口管制时应该加强外贸风险的识别和管理，针对不同的风险采取差别化的防范和化解措施。  相似文献   

农机投入对农业GTFP影响及门槛效应的区域差异分析     

刘敏  姜会明  姜天龙 《地理科学》2020,40(12):2037-2045

按照粮食的产销情况，将全国划分为3类粮食功能区域，利用固定效应模型和门槛效应模型分析了农机投入对农业绿色全要素生产率（GTFP）的影响及门槛效应的区域差异。结果表明：农机投入对农业GTFP的影响程度存在区域异质性，农机投入对粮食主销区农业GTFP提升的促进作用最大，粮食产销平衡区次之，粮食主产区最小；农机投入对农业GTFP的影响路径亦存在区域差异，粮食主产区和产销平衡区的农机投入通过促进农业技术效率和农业技术进步进而推动农业GTFP提升，粮食主销区的农机投入通过促进农业技术进步推动农业GTFP提升；农机投入对粮食主产区农业GTFP的影响存在双门槛效应，对粮食主销区和产销平衡区农业GTFP的影响存在单门槛效应。  相似文献   

通过课堂观察提升教师课程知行力的探究     

秦江 《地理教学》2020,(4):57-58,32

课堂是实施课程育人的主阵地,教师的教育观、课程观、课堂观、学生观等在课堂中的具体体现,反映了教师课程知行力的水平。本文以课程知行力的视角,探讨课堂观察的目的、内容和方法,并通过案例剖析的方式,为一线教师开展课堂观察,更新教育观念和教学方式,提升课程知行力提供参考。  相似文献   

Correspondence between the large volcanic eruptions and ENSO events over AD 1525–2000     

Fang  Xiuqi  Zheng  Xue  Zhang  Xing 《地理学报(英文版)》2020,30(1):103-118

ENSO is an interannual mode which may be affected by external forcing, such as volcanic eruptions. Based on the reconstructed volcanic eruptions chronology and ENSO sequences, both 195 large volcanic eruptions(VEI≥4) and 398 ENSO(El Ni?o and La Ni?a) events were extracted from 1525 to 2000. An analysis of the correspondence between the large volcanic eruptions and ENSO events was performed by matching the large volcanic eruptions with the types and magnitudes of ENSO events present in the 0–2 years after the eruptions. The results show the following:(1) The percentages of ENSO events within the 3 years after the large eruptions had increased to 68.3% from 31.7% compared with those with no-eruptions in the previous 0–2 years. In addition, the ratio of El Ni?o to La Ni?a events turned from 2:3 to 1:1, and more El Ni?o events occurred in the 0 year after eruptions in the low-latitudes of the Northern Hemisphere and in the tropics but more La Ni?a events occurred in the 0 year after in the high-latitudes of the Northern Hemisphere and the Southern Hemisphere.(2) After the eruptions, the weak(W) El Ni?o events had increased by 8 percentage points and the very strong(VS) El Ni?o events had decreased by 10 percentage points; conversely, there was a decrease by 15 percentage points of the weak La Ni?a events and an increase by 11.4 percentage points of the very strong La Ni?a events. Specifically, the percentages of strong La Ni?a events increased to a peak at 1(+1) year after the eruptions.(3) The percentage of eruptions followed by single-year ENSO was the greatest. The percentage of ENSO events that occurred in the consecutive 2 years following an eruption was approximately equal to the percentage of events that occurred consecutively 3 years following an eruption, and both sets of ENSO magnitudes showed a decreasing trend.  相似文献   

Geological Control of Fold Structure on Gas Occurrence and Its Implication for Coalbed Gas Outburst: Case Study in the Qinan Coal Mine,Huaibei Coalfield,China     

Zhang  Kaizhong  Wang  Liang  Cheng  Yuanping  Li  Wei  Kan  Jin  Tu  Qingyi  Jiang  Jingyu 《Natural Resources Research》2020,29(2):1375-1395

  相似文献   

空间分析与生物地球化学循环:西藏林周县大骨节病患病村与非患病村的比较研究     

田原  查欣洁  高星  戴尔阜  余成群 《资源与生态学报(英文版)》2020,11(2):232-246

西藏林周县是我国大骨节病(KBD)患病较为严重的地区之一,本文将林周县作为研究区,通过使用地理探测器(GeoDetector)量化分析KBD患病率风险因子的影响,并使用环境化学方法验证空间分析结果。通过对10个潜在影响因子的分析以及对当地KBD患病村和非患病村的土壤-水-粮食-人这一生物地球化学循环的环境化学分析,结果表明:(1)林周县KBD由一组多重且交互作用的环境影响因子共同作用影响,其中最重要的控制因子是地层因子;(2)所有环境介质(土壤、水、谷物)及人体组织中的硒元素浓度在KBD患病区均低于非患病区;(3)当地居民对硒和铬的摄入严重不足,尤其是KBD患病村中居民硒元素平均日摄入量(ADD)大约仅为世界卫生组织(WHO)建议的成人基本摄入量下限的4%;(4)我们推测,当地居民患病主要是由于地层这一影响因子,这是由于通过生态系统的迁移转化导致当地人口严重硒缺乏,最终导致地方性生物地球化学硒缺乏。  相似文献   

石榴石微量元素地球化学及其在沉积物源分析中的应用     

洪东铭  简星  黄鑫  张巍  马金戈 《地学前缘》2020,27(3):191-201

石榴石是沉积物中常见的重矿物,其可来源于多种岩石,而且不同类型母岩中石榴石具有多样的地球化学组成,因此碎屑石榴石的地球化学分析在沉积物源研究中应用广泛。通过电子探针分析可以容易地获得单颗粒碎屑石榴石的主量元素地球化学组成,可借此探讨其母岩类型,但也存在一定的局限性,比如中酸性火成岩和部分变沉积岩来源的石榴石通常都具有高Fe、Mn的特征,不易于区分。本文系统地收集了不同岩石类型的石榴石微量元素数据,尝试利用微量元素地球化学的差异性对碎屑石榴石物源分析进行补充。最终得出以下结论:(1)石榴石的稀土元素(REE)组成与钇(Y)元素指标可区分中酸性火成岩和变沉积岩来源的碎屑石榴石;(2)基性岩(橄榄岩、辉石岩)及所对应的变基性岩石(榴辉岩)中石榴石的微量元素地球化学组成相近,但部分橄榄岩来源的石榴石在镨/钬(Pr_N/Ho_N)值和重稀土总量(ΣHREE含量)上与辉石岩和榴辉岩的有显著差别,这一特点可运用于以基性岩母岩为主的碎屑沉积物源研究中;(3)夕卡岩中的石榴石在主量元素地球化学组成上表现为高度一致的高Ca特征,而稀土元素组成具有两种典型的分配模式,岩浆型(指示富铁、氧化环境)与热液型(指示富铝、还原环境)。综上所述,石榴石微量元素地球化学可以有效地运用于沉积物源分析研究中,是其主量元素物源分析方法的重要补充。  相似文献   

城市居民日常身体活动时空分异特征及影响因素   总被引：2，自引：2，他引：0  

姜玉培  甄峰  赵梦妮  曹晨 《地理科学》2019,39(9):1496-1506

依托南京主城区居民日常身体活动调查数据,基于身体活动时空维度,挖掘城市居民日常身体活动时空分异特征,并采用混合效应模型探究身体活动分异的影响因素。研究表明：① 居民日常身体活动时空异质特征明显。工作日/非工作日不同类型身体活动时间安排及个体间差异均显著;工作性、交通性、家务性身体活动空间制约明显,而休闲性身体活动空间分布更具弹性;与工作日相比,非工作日不同类型身体活动空间范围变化收敛与扩散特征并存。② 活动空间范围、个人社会经济属性、自身健康状况对居民日常身体活动分异均具有显著影响。具体而言,居民日常活动空间范围决定身体活动的空间适应与选择;社会分工差异导致不同性别、年龄人群身体活动具有指向性;身体活动时间出现与个人社会经济实力倒置现象;而良好健康状态会激励居民日常身体活动的保持。  相似文献   

基于专利的石漠化治理技术分析     

宁宝英  马建霞  姜志德 《中国沙漠》2019,39(5):135-142

石漠化是发生面积仅次于沙漠化的荒漠化类型，已成为中国西南喀斯特山区可持续发展的主要障碍，其治理与恢复是复杂的系统工程。从治理技术层面，以1 159组简单专利族为数据基础，揭示国内石漠化治理技术类别分布和主要领域。在对专利进行简要计量分析以提供概貌认识的基础上，通过阅读专利摘要内容，采用自下而上的聚类方法将当前专利划分为石漠化判断、治理、产业经济3个大类，监测与评价、科研仪器、生物治理、工程治理、化学治理、综合治理、综合产业、农业和工业9个中类，更细分至雨水搜集净化等42个小类。根据专利数量认定的四大主要技术领域为：工程治理（8.63%）、水分利用（12.51%）、栽培种植（27.52%）、植物资源加工（9.67%），占总量的58.33%，专利领域分布相对集中。对主要技术领域采用内容分析法，提取工程治理具体措施、集雨工具、植物、加工制品等的信息并对其进行了详细阐述，指出目前专利技术中的问题：石漠化地区特有的植物资源众多，但目前加工层次偏低，应在拓展加工类型、延长加工产业链条、发掘植物药用和日用价值方面加大研发力度；防止土壤漏失技术、设施农业技术和生命基因技术亟待发展。分析可为全面认识国内石漠化治理技术提供专利视角的参照。  相似文献